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Can I send emails from anonmails.de?

No, anonmails.de is not an email providing service. You can only receive, read and save emails.

Is there any size limitation?

The maximum size of a message is limited to 5 MB. The inbox is limited to 30 MB.

How can I use POP3 or POP3S?

POP3S configuration with Thunderbird:
POP3S